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Rapid growth of fully-inorganic flexible CaxCoO2 thin films from a ligand free aqueous precursor ink for thermoelectric applicationsopen access

Authors
Sinha, Tridib KumarLee, JinhoKim, Jin KukRay, Samit K.Paul, Biplab
Issue Date
11-Jul-2019
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.55, no.54, pp 7784 - 7787
Pages
4
Indexed
SCI
SCIE
SCOPUS
Journal Title
CHEMICAL COMMUNICATIONS
Volume
55
Number
54
Start Page
7784
End Page
7787
URI
https://scholarworks.gnu.ac.kr/handle/sw.gnu/8954
DOI
10.1039/c9cc03441b
ISSN
1359-7345
1364-548X
Abstract
We demonstrate a ligand-free green chemical method for the rapid growth of nanoporous Ca0.35CoO2 thin films on sapphire and mica substrates from a water-based precursor ink, formulated by dissolving the precursor solid, composed of in situ prepared Ca2+-DMF and Co2+-DMF complexes. Mica serves as the flexible substrate as well as the sacrificial layer for the film transfer. Despite the presence of nanopores, the power factor of the flexible film Ca0.35CoO2-on-mica is above 0.50 x 10(-4) W m(-1) K-2 at around room temperature. The present technique is simple and cost-effective.
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