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리튬이온전지용 난연성 첨가제(TCP, TFPP)의 전기화학적 특성Electrochemical Performance of Tricredyl Phosphate and Trispentafluorophenly Phosphine as Flame Retardant Additives forLithium-ion Batteries
- Other Titles
- Electrochemical Performance of Tricredyl Phosphate and Trispentafluorophenly Phosphine as Flame Retardant Additives forLithium-ion Batteries
- Issue Date
- Sep-2007
- Publisher
- 한국전기전자재료학회
- Keywords
- Electrolytes; Flame retardant; Li-ion battery; TCP; TFPP; Electrolytes; Flame retardant; Li-ion battery; TCP; TFPP
- Citation
- 전기전자재료학회논문지, v.20, no.9, pp 756 - 760
- Pages
- 5
- Indexed
- KCI
- Journal Title
- 전기전자재료학회논문지
- Volume
- 20
- Number
- 9
- Start Page
- 756
- End Page
- 760
- ISSN
- 1226-7945
2288-3258
- Abstract
- Flame retardant(FR) properties were investigated with tricredyl phosphate(TCP) and tris(pentafluorophenyl)phosphine(TFPP) as additives for lithium-ion batteries. Thermal stability was improved with additives in Li/LiNi⅓Mn⅓Co⅓O₂cells comparing to non-additive electrolytes. Oxygen evolution reaction of the cathode material was delayed to up 55 ℃, from 275 ℃ to 330 ℃. Electrolytes with the 1 wt.% additives provided good FR properties while the resonable battery performance is maintained.
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