Preparation of cubic SiC from δ-Na<sub>2</sub>Si<sub>2</sub>O<sub>5</sub>/carbon nanocomposite using cobalt catalyst

Abstract

Silicon carbide (SiC) was prepared by carbothermal reduction of a crystalline-layered sodium silicate (delta-Na2Si2O5)/carbon nanocomposite (LCN), which contained a stacked carbon film embedded with cobalt between the silicate layers. Subsequent sintering of this mixture for 3 h at 1000-1350 degrees C resulted in the formation of graphitic carbon and SiC. Meanwhile, sintering without a cobalt catalyst resulted in the formation of graphitic carbon, regardless of the temperature. The use of a cobalt catalyst allowed the formation of a pure SiC phase at 1350 degrees C. The formed SiC had an irregular worm-like morphology, with a particle size of similar to 5 mu m. The Brunauer-Emmett-Teller surface areas of graphitic carbon and SiC were 28-150 and similar to 7.0 m(2)/g, respectively. We concluded that graphite and SiC were produced at this low sintering temperature because of the cobalt catalyst, which facilitated nanomixing of carbon and SiO2 by sandwiching the carbon films between the silicate layers.