Detailed Information
Cited 12 time in 
Cited 12 time in 
Cited 12 time in
Metadata Downloads
Pentacyclic Nano-Trefoil
- Authors
- Ju, Huiyeong; Tsuruoka, Yumiko; Hayano, Miho; Lee, Eunji; Park, Ki-Min; Ikeda, Mari; Ishi-i, Jun-ichi; Kuwahara, Shunsuke; Habata, Yoichi
- Issue Date
- Jan-2021
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- argentivorous molecules; cyclen; cyclic dimers; pentacyclic trefoil; reversible structural transformation; silver(I) complexes
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.60, no.2, pp 650 - 654
- Pages
- 5
- Indexed
- SCIE
SCOPUS
- Journal Title
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Volume
- 60
- Number
- 2
- Start Page
- 650
- End Page
- 654
- ISSN
- 1433-7851
1521-3773
- Abstract
- Tetra-armed cyclen (1) bearing two 4-(4'-pyridyl)benzyl and two 3,5-difluorobenzyl groups and its Ag+ complexes were prepared and structurally characterized. The complexes formed between 1 and Ag+ undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil complex with changes in the Ag+/ 1 molar ratio. It was also revealed that the 3:5 trefoil complex could encapsulate benzene and [D6]benzene selectively in solid-state. The benzene-included structures are stabilized by C-H center dot center dot center dot F-C interactions between the benzene molecule and the ligand molecule.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - ETC > Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.