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Synthesis of a small molecular cage consisting of three aminomethyl pyrroles and its selective fluoride recognition
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | 허남중 | - |
| dc.contributor.author | 한혜진 | - |
| dc.contributor.author | 최재원 | - |
| dc.contributor.author | 김성국 | - |
| dc.date.accessioned | 2023-01-02T05:23:01Z | - |
| dc.date.available | 2023-01-02T05:23:01Z | - |
| dc.date.issued | 2022-12 | - |
| dc.identifier.issn | 1226-6531 | - |
| dc.identifier.uri | https://scholarworks.gnu.ac.kr/handle/sw.gnu/29437 | - |
| dc.description.abstract | A small cage-like molecule (2) composed of three aminomethyl pyrroles and two hexa-substituted benzenes has been prepared by reduction of its iminopyrrole analogue (1) using NaBH4. It was revealed by 1H NMR spectroscopic analyses that cage molecule 2 strongly binds the fluoride anion in polar DMSO-d6 relative to CDCl3. Compared to that of compound 1, the lowered affinity of 2 for the fluoride anion is attributable to its increased electron density resulting from the production of thesecondary amine groups. | - |
| dc.format.extent | 6 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | 한국자기공명학회 | - |
| dc.title | Synthesis of a small molecular cage consisting of three aminomethyl pyrroles and its selective fluoride recognition | - |
| dc.title.alternative | Synthesis of a small molecular cage consisting of three aminomethyl pyrroles and its selective fluoride recognition | - |
| dc.type | Article | - |
| dc.publisher.location | 대한민국 | - |
| dc.identifier.doi | 10.6564/JKMRS.2022.26.4.040 | - |
| dc.identifier.wosid | 000972548200001 | - |
| dc.identifier.bibliographicCitation | Journal of the Korean Magnetic Resonance Society, v.26, no.4, pp 40 - 45 | - |
| dc.citation.title | Journal of the Korean Magnetic Resonance Society | - |
| dc.citation.volume | 26 | - |
| dc.citation.number | 4 | - |
| dc.citation.startPage | 40 | - |
| dc.citation.endPage | 45 | - |
| dc.type.docType | Article | - |
| dc.identifier.kciid | ART002905669 | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | esci | - |
| dc.description.journalRegisteredClass | kci | - |
| dc.relation.journalResearchArea | Biochemistry & Molecular Biology | - |
| dc.relation.journalWebOfScienceCategory | Biochemical Research Methods | - |
| dc.subject.keywordAuthor | molecular cage | - |
| dc.subject.keywordAuthor | anion recognition | - |
| dc.subject.keywordAuthor | fluoride | - |
| dc.subject.keywordAuthor | affinity | - |
| dc.subject.keywordAuthor | selectivity | - |
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