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Cited 59 time in webofscience Cited 57 time in scopus
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Calix[4]thiacrowns as ditopic hosts for homo- and heterobinuclear accommodation: First report of a chopsticks-type pi-coordination

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dc.contributor.authorLee, Jai Young-
dc.contributor.authorKwon, Jongchul-
dc.contributor.authorPark, Chul Soon-
dc.contributor.authorLee, Ji-Eun-
dc.contributor.authorSim, Wonbo-
dc.contributor.authorKim, Jong Seung-
dc.contributor.authorSeo, Joobeom-
dc.contributor.authorYoon, Il-
dc.contributor.authorJung, Jong Hwa-
dc.contributor.authorLee, Shim Sung-
dc.date.accessioned2022-12-27T07:03:27Z-
dc.date.available2022-12-27T07:03:27Z-
dc.date.issued2007-02-01-
dc.identifier.issn1523-7060-
dc.identifier.issn1523-7052-
dc.identifier.urihttps://scholarworks.gnu.ac.kr/handle/sw.gnu/28444-
dc.description.abstractCalix[4]thiacrowns with hetero-(1) and a homodonor set (L-2) were synthesized and characterized by X-ray analysis. From the reaction of L-2 with AgPF6, disilver complex [Ag-2(L-2)](PF6)(2) (1) was isolated. By comparing 1,3-alternate conformations of L-2 and 1, we found a considerable decrease of dihedral angles of two opposite aromatic rings upon complexation. This finding can be explained in terms of the "chopsticks process", which illustrates how Ag+-arene pi-coordination occurs. Heterobinuclear complexation of L-1 in solution was also observed.-
dc.format.extent4-
dc.language영어-
dc.language.isoENG-
dc.publisherAMER CHEMICAL SOC-
dc.titleCalix[4]thiacrowns as ditopic hosts for homo- and heterobinuclear accommodation: First report of a chopsticks-type pi-coordination-
dc.typeArticle-
dc.publisher.location미국-
dc.identifier.doi10.1021/ol062863o-
dc.identifier.scopusid2-s2.0-33847063889-
dc.identifier.wosid000243706400029-
dc.identifier.bibliographicCitationORGANIC LETTERS, v.9, no.3, pp 493 - 496-
dc.citation.titleORGANIC LETTERS-
dc.citation.volume9-
dc.citation.number3-
dc.citation.startPage493-
dc.citation.endPage496-
dc.type.docTypeArticle-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusSUPRAMOLECULAR SILVER(I) COMPLEXES-
dc.subject.keywordPlusMETAL ION CHEMISTRY-
dc.subject.keywordPlus1,3-ALTERNATE CONFORMATION-
dc.subject.keywordPlusCYCLIC POLYETHERS-
dc.subject.keywordPlusLIGAND ISOMERISM-
dc.subject.keywordPlusRARE EXAMPLE-
dc.subject.keywordPlusDONOR SETS-
dc.subject.keywordPlusMACROCYCLES-
dc.subject.keywordPlusCALIX<4>ARENES-
dc.subject.keywordPlusRECOGNITION-
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