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Synthesis and Physical Properties of Decylbithiophene End-Capped Oligomers Based on Naphthalene, Anthracene and Benzo[1,2-b:4,5-b']dithiophene
- Authors
- Jang, Sang Hun; Tai, Truong Ba; Kim, Min Kyu; Han, Jeong Woo; Kim, Yun-Hi; Shin, Sung Chul; Yoon, Yong Jin; Kwon, Soon Ki; Lee, Sang-Gyeong
- Issue Date
- Mar-2009
- Publisher
- 대한화학회
- Keywords
- Suzuki coupling; Photoluminescence; Cyclic voltametry; Thermal gravimetric analysis; Differential scanning calorimetry
- Citation
- Bulletin of the Korean Chemical Society, v.30, no.3, pp 618 - 622
- Pages
- 5
- Indexed
- SCIE
SCOPUS
KCI
- Journal Title
- Bulletin of the Korean Chemical Society
- Volume
- 30
- Number
- 3
- Start Page
- 618
- End Page
- 622
- ISSN
- 0253-2964
1229-5949
- Abstract
- The new candidates for OTFTs, which were composed of naphthalene, anthracene, benzo[1,2-b:4,5-b']dithiophene and 2-decylbithiophene end-capper were synthesized under Suzuki coupling reaction conditions. All of the oligomers were characterized by FT-IR, mass analysis, UV vis, PL spectrum, cyclic voltametry (CV), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), H-1-NMR and C-13-NMR. Investigation of physical properties showed that all of the oligomers have higher oxidation potential and good thermal stability. Especially, DBT-DtB-DBT is soluble in common solvents and suitable for low cost processing technologies.
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