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Fabrication and electrical properties of Si-based La10-xBix(SiO4)(6)O-3 apatite ionic conductor

Authors
Kim, Dae-YoungLee, Sung-Gap
Issue Date
Oct-2012
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
Ceramics; Impedance spectroscopy; Crystal structure; Ionic conductivity
Citation
MATERIALS RESEARCH BULLETIN, v.47, no.10, pp 2856 - 2858
Pages
3
Indexed
SCI
SCIE
SCOPUS
Journal Title
MATERIALS RESEARCH BULLETIN
Volume
47
Number
10
Start Page
2856
End Page
2858
URI
https://scholarworks.gnu.ac.kr/handle/sw.gnu/22005
DOI
10.1016/j.materresbull.2012.04.056
ISSN
0025-5408
1873-4227
Abstract
In this paper we report an investigation about the relationship between Bi content and conductivity for the La10-xBix(SiO4)(6)O-3 (x = 0.5-2) specimens. Increasing Bi content in apatite-type La10-xBix(SiO4)(6)O-3 specimen leads to increasing the average grain size and sinterability because some Bi ion deposited at grain boundaries which promotes grain growth. The relative sintered density of the La8Bi2(SiO4)(6)O-3 specimen is 98%. There is a small shift in diffraction angle of XRD peaks, complicated lattice distortion was observed in the X-ray pattern with increasing content of Bi. Electrical conductivity of La10-xBix(SiO4)(6)O-3 specimen increased with increasing Bi contents and the value of the La8Bi2(SiO4)(6)O-3 specimen is 2.4 x 10(-4) S cm(-1) at 700 degrees C. (C) 2012 Elsevier Ltd. All rights reserved.
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Lee, Sung Gap
대학원 (나노신소재융합공학과)
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