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Construction and characterization of novel molecular architectures through coordination-driven self-assembly: rhomboid and overlapped double rhomboid
- Issue Date
- Aug-2014
- Publisher
- SPRINGER
- Keywords
- Molecular architecture; Self-assembly; Ligand; Platinum; Rhomboid; Supramolecule
- Citation
- JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, v.79, no.3-4, pp 495 - 502
- Pages
- 8
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
- Volume
- 79
- Number
- 3-4
- Start Page
- 495
- End Page
- 502
- ISSN
- 1388-3127
1573-1111
- Abstract
- The potentially tridentate ligands 4-(6-(pyridin-4-yl)pyridin-2-yl)pyridine (4) and 3-(6-(pyridin-3-yl)-pyridin-2-yl)pyridine (5) have been prepared and characterized. From the self-assembly of 4 or 5 and 2,9-bis[trans-Pt(PEt3)(2)(NO3)]phenanthrene (6), two supramolecular platinum-based macrocycles with rhomboid (7) and overlapped double rhomboid (8) structures have been constructed. Compounds 7 and 8 are formed in different shapes due to the different nitrogen positions (meta and para) of the ligands 4 and 5, respectively. Both supramolecules are characterized by multinuclear NMR and electrospray ionization mass spectroscopies.
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