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Ship in a breakable bottle: fluoride-induced release of an organic molecule from a Pr(III)-linked molecular cage
- Authors
- Lee, Juhoon; Waggoner, Nolan W.; Polanco, Luis; You, Ga Rim; Lynch, Vincent M.; Kim, Sung Kuk; Humphrey, Simon M.; Sessler, Jonathan L.
- Issue Date
- 2016
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- CHEMICAL COMMUNICATIONS, v.52, no.55, pp 8514 - 8517
- Pages
- 4
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- CHEMICAL COMMUNICATIONS
- Volume
- 52
- Number
- 55
- Start Page
- 8514
- End Page
- 8517
- ISSN
- 1359-7345
1364-548X
- Abstract
- A 3-dimensional networked molecular cage, NMC-1, has been synthesized. This macrocycle-based framework was prepared from a solvothermal reaction involving a flexible organic building block, calix[4] pyrrole dibenzoic acid (H2L), and Pr(NO3)(3)center dot 6H(2)O. A unique feature of NMC-1 is that it retains free calix[4]pyrrole molecules in the framework pores. Treatment with a fluoride anion source serves to destroy the network and allows release of the organic guest. The net result is a 'molecular ship' in a 'breakable bottle'.
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