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Synthesis of Thienopyrrolodione-Based Copolymers and Their Application in Organic Thin-Film Transistors
- Authors
- Lee, Ji Eun; Kim, Yebyeol; Ha, Jong-Jin; An, Tae Kyu; Kim, Yun-Hi
- Issue Date
- Aug-2017
- Publisher
- American Scientific Publishers
- Keywords
- Organic Transistors; Polymeric Semiconductor; Thienopyrrolodione
- Citation
- Journal of Nanoscience and Nanotechnology, v.17, no.8, pp 5662 - 5668
- Pages
- 7
- Indexed
- SCIE
SCOPUS
- Journal Title
- Journal of Nanoscience and Nanotechnology
- Volume
- 17
- Number
- 8
- Start Page
- 5662
- End Page
- 5668
- ISSN
- 1533-4880
1533-4899
- Abstract
- Two thienopyrrolodione (TPD)-based polymers, 24DTT-TPD and 24DTS-TPD, were synthesized bycarrying out Stille coupling reactions. The obtained polymers were characterized by H-1 NMR, FT-IR, mass analysis, UV-visible spectroscopy, cyclic voltammetry, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The deposited films were characterized by X-ray diffraction. Synthesized polymers showed good solubility in common solvents. The solution-processed organic field-effect transistors showed field-effect mobility values of 4.5x10(-5) cm(2)/Vs for 24DTT-TPD and 2.9x10(-2) cm(2)/Vs for 24DTS-TPD at optimal conditions.
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