Synthesis and Characterization of New TPD-based Copolymers and Applications in Bulk Heterojunction Solar Cells
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초록

We developed and synthesized two novel polymeric semiconductor materials containing thienopyrrolodione (TPD) units, with one of the polymers also containing thiophene (T) units and the other containing bi-thiophene (BT) units, and denoted as TPD-T and TPD-BT, respectively. TPD-T and TPD-BT were studied for bulk heterojunction organic solar cells as blends with [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM). The TPD-T-based device exhibited considerably better photovoltaic performances, with a power conversion efficiency of 2.51%, in contrast to the 1.63% value for the TPD-BT-based device. According to atomic force microscope images of the TPD-BT:PC71BM and TPD-T:PC71BM blend films, the latter showed more nanoscale phase aggregation, explaining its better photovoltaic properties.

키워드

organic solar cellpolymerenergy devicebulk heterojunctionsthienopyrrolodioneFIELD-EFFECT TRANSISTORSCONJUGATED POLYMERSCONVERSION EFFICIENCYDESIGNDONORACCEPTORSOLVENTDIKETOPYRROLOPYRROLEPERFORMANCESAGGREGATION
제목
Synthesis and Characterization of New TPD-based Copolymers and Applications in Bulk Heterojunction Solar Cells
저자
Cheon, HyunginKim, Yu JinHwang, Moon ChanHong, JisuAn, Tae KyuKwon, Soon-KiKim, Yun-Hi
DOI
10.1007/s13233-018-6011-6
발행일
2018-01
유형
Article
저널명
Macromolecular Research
26
1
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29 ~ 34